Search results for "Thermal propertie"

Renewable polyol obtained by microwave-assisted alcoholysis of epoxidized soybean oil: Preparation, thermal properties and relaxation process

2019

[EN] The soybean oil polyol (SOP) use as feedstock in the polyurethane industry has been recently emphasized due to its excellent resistance to hydrolysis, which is also applicable in coatings and thermal insulation. In this article, the SOP was obtained by a very fast microwave-assisted alcoholysis of epoxidized soybean oil (ESO). The preparation method, thermal properties, and relaxation process were evaluated. High yields as opening and consumption epoxy group and selectivity of 99.8 mol%, 985 mol%, and 71.2 mol% were obtained. Through titrations, nuclear magnetic resonance and gel permeation chromatography were identified parameters as 0.32 mg KOH.g(-1) acid number, 190 mg KOH.g(-1) hyd…

An innovative approach to manage uncertainties and stock diversity in the EPBD cost-optimal methodology

2018

The EU Energy Performance of Buildings Directive (EPBD) 2010/31/EU is a step in the right direction to promote near zero energy buildings (NZEB) in a step-wise manner, starting with minimum energy performance and cost optimal thresholds for “reference buildings” (RBs) for each category. Nevertheless, a standard method for defining RBs does not exist, which led to a great divergence between MS in the level of detail used to define RBs for the EPBD cost-optimal analysis. Such lack of harmonisation between MS is further evident given the resulting large discrepancies in energy performance indicators even between countries having similar climate. Furthermore, discrepancies of 30% or higher betw…

Soil water content monitoring: a verification of thermal inertia approaches on low spatial, high temporal resolutions images

2013

Soil water content is directly connected with soil evaporation and plant transpiration processes; in particular, soil water content within the root zone, is readily available to evapotranspiration. Thus, in agricultural sciences, the assessment of the spatial distribution of soil water content could be of utmost importance in evaluating crop water requirement. In spite of limitations to applicability due to contingent cloud cover, water content of the upper part of the soil can be determined by applying the thermal inertia approach by coupling optical and thermal infrared images. The thermal inertia formulation, rigorously retrieved on bare soil, has been also verified on soils partially co…

Characterization of electrospun poly(lactide) composites containing multiwalled carbon nanotubes

2019

The author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: The authors would like to thank the Ministry of Education, Science and Technological Development, Republic of Serbia, for funding projects III45022 and 172056 and European Cooperation in Science and Technology (COST) action CA15107.

A systematic literature review on less common natural fibres and their biocomposites

2018

Abstract Interest in utilization of renewable resources is increasing because of public's environmental awareness and economic considerations. Lignocellulosic fibres have already attracted growing attention as reinforcement of polymeric matrices instead of synthetic ones (mainly glass) from the academic and industrial fields. In addition to kenaf, hemp, sisal, flax and jute, which are the subject of extensive investigations for composite applications since the 1970s, in the last years several researchers suggested the use of less common natural fibres, due to their low cost and availability. This paper reviews the extraction methods, chemical, morphological, thermal and mechanical propertie…

SYNTHESIS AND CHARACTERISATION OF NEW AZOLE BUILDING BLOCKS FOR FUNCTIONAL IONIC SYSTEMS

The synthesis of a series of 27 salts based on 5-(4-(alkyloxy)phenyl)-1,4-dimethyl-3-(perfluoroalkyl)-1,2,4-triazol-4-ium structures, differing in the length of the alkyl and perfluoroalkyl chains, as well as in the counter ions is reported. Some properties of this new family of salts as perspective liquid-crystalline ionic liquids (LC-ILs) are described and the influence of the varying moieties in the modulation of the properties is discussed.

High resolution remote estimation of soil surface water content by a thermal inertia approach

2009

Summary The spatial distribution of soil surface water content in a bare soil was evaluated by a thermal inertia approach from high resolution visible/near infrared (VIS/NIR) and thermal infrared (TIR) airborne data. Given that the relationship between the thermal inertia and the soil water content strongly depends on the accurate estimation of the soil thermal conductivity, two different empirical models were applied to estimate it. Remotely estimated water contents were tested with time domain reflectometry (TDR) measurements collected on a 110 × 90 m 2 bare field in coincidence with airborne over-flights. The thermal conductivity model by Johansen (1975) produced more accurate estimates …

Critical analysis of empirical ground heat flux equations on a cereal field using micrometeorological data

2009

The rate at which the net radiation is transferred to the soil as ground heat flux varies with surface characteristics. Surface energy balance algorithms use empirical relationships taking into account the effects of the canopy cover to insulate the soil through vegetation indexes, the soil capacity to absorb incoming net radiation via the albedo, and the surface temperature promoting the energy transfer. However empirical relationships are often dependent on local conditions, such as the soil humidity and vegetation type. Ground heat flux assumes a minimum value in case of full canopy cover and a maximum value for dry bare soil. Aim of the present research is the critical analysis of some …

Assessing the performance of thermal inertia and Hydrus models to estimate surface soil water content

2017

The knowledge of soil water content (SWC) dynamics in the upper soil layer is important for several hydrological processes. Due to the difficulty of assessing the spatial and temporal SWC dynamics in the field, some model-based approaches have been proposed during the last decade. The main objective of this work was to assess the performance of two approaches to estimate SWC in the upper soil layer under field conditions: the physically-based thermal inertia and the Hydrus model. Their validity was firstly assessed under controlled laboratory conditions. Thermal inertia was firstly validated in laboratory conditions using the transient line heat source (TLHS) method. Then, it was applied in…

Ionic liquid crystals based on 3-perfluoalkyl-1,2,4-triazol-4-ium salts

2016

Liquid-crystalline ionic liquids (LC-ILs) are a class of organic materials that of great current interest: they are defined as organic salts that possess the properties of two interesting kinds of material – ionic liquids (ILs) and liquid crystals (LCs). LC-ILs combine many interesting features of ILs (e.g. low volatility and the ability to dissolve solutes with a range of polarities) as well as many attractive properties of LCs (e.g. their intrinsic order and anisotropy). This provides unique opportunities that can be exploited in many different fields, for example their use as solvents for extraction processes as well as electrolytes for batteries, fuel cells, and dye-sensitised solar cel…